Calorimetry post lab answers

May 17, 2011 ... Solutions. Chem Academy · Playlist · 56:24. Go to channel · Energetics 2 | Calorimetry | Enthalpy Change Experiments | A level. The Chemistry .....

Calorimetry post lab answers. It will be determined from your Excel graph. A 25.39 g sample of metal is heated to 98.6°C in a hot water bath until thermal equilibrium is reached. The metal is quickly transferred to 50.0 mL (50.0 g) of water at 22.2°C contained in a calorimeter. The thermal equilibrium temperature of the metal sample plus water mixture is 28.3°C.

Chemistry questions and answers. Experiment 25 Prelaboratory Assignment Calorimetry ateLab Sec.Name 1. Experimental Procedure, Desk No. Part A.1. What is the procedure for heat ing a metal to an exact but measured temperature? 2 Experimental Procedure, Parts A.4, 5 a. When a metal at a higher temperature is transferred to water at a lower ...

heat released by reaction( − qreaction) = heat absorbed by reaction mixture( + qmixture) = (m × c × ΔT)mixture. Here m is the total mass of the reaction mixture (in g), ΔT is the maximum temperature change that occurs during the reaction (in °C), and c is the specific heat capacity of the mixture (in J/g°C). Note that since the ...Take an immersive audio visual tour of IBM's Q lab where the company researches quantum computers. IBM just released an immersive audio visual tour of their Q lab, where the compan...Take an immersive audio visual tour of IBM's Q lab where the company researches quantum computers. IBM just released an immersive audio visual tour of their Q lab, where the compan...The first time a student solved this problem she got an answer of 88 °C. Explain why this is clearly an incorrect answer. Answer a. 81.95 °C. Answer b. This temperature is higher than the starting temperature of the coffee, which is impossible. Click here to see a video of the solutionDec 10, 2020 ... Correction: at 3:00, I say that everything on the slide is an intensive property. While that is true for specific heat capacity and molar ...Question: Experiment 10 -Calorimetry and Specific Heat of Water Answer the following Pre-laboratory questions and problems and Post questions and problems and include in your Experiment 10 - Calorimetry and Specific Heat of Water. I Pre - Lab Answer the following. 1)The Styrofoam cups used in this calorimetry experiment is an insulated …

17.7: Calorimetry. At one time, calories in foods were measured with a bomb calorimeter. A weighed amount of the food would be placed in the calorimeter and the system was then sealed and filled with oxygen. An electric spark ignited the food-oxygen mixture. The amount of heat released when the food burned gave an idea of the calories present ...LAB REPORT FOR EXPERIMENT 2. NAME: JERALDINE CABAWATAN COURSE: BS in Civil Engineering GROUP: Group – 2 DATE SUBMITTED: November 7, 2020 SIGNATURE: Coffee Cup Calorimetry A. 1. COFFEE CUP CALORIMETRY VIDEO. a. In thermodynamics, define (a) the system and (b) the surroundings.Chemistry questions and answers; CHM 2045 - Hear Effects and Calorimetry Post-Lab Sheet: Heat Effects and Calorimetry Name: Show calculations for credit. Be mindful of significant figures. 1. A piece of aluminum with a mass of 32.5 g is heated to 67.4C and put into a Styrofoam calorimeter containing 58.2 g of water that is initially at 21.2°C.heat released by reaction( − qreaction) = heat absorbed by reaction mixture( + qmixture) = (m × c × ΔT)mixture. Here m is the total mass of the reaction mixture (in g), ΔT is the maximum temperature …CALORIMETRY Post-lab Questions Date Name Partners) 1. Use the table of Thermodynamic Properties at 298 K found in Appendix A.2 of your IGC e-textbook to calculate 4G . H and sº for the net ionic equation for the strong acid-strong base neutralization shown below: H:0"(aq) + OH-(aq) → H:0() + H:0(1) Haq) + OH-(aq) → …General Chemistry Laboratory I100% (1) 1. ID of a Compound Postlab. General Chemistry Laboratory INone. 4. Mastery Course Plan - This is about Lecture. General Chemistry …Proto Labs News: This is the News-site for the company Proto Labs on Markets Insider Indices Commodities Currencies Stocks

Answer 123 - chem. Introductory University Chemistry I None. POST LAB REPORT EXPERIMENT A experiment calorimetry for the chem 10x …Chapter 7 Periodic Trends of Elements. Molarity Pogil Worksheet. Scientific Methods Practice. S2-2-07 -The Flaming Snowball - Discrepant Event. Inform - ddadasdadacadcadcqawcdw. All answers name: date: student exploration: calorimetry lab vocabulary: calorie, calorimeter, joule, specific heat capacity gizmo calorimeter is an insulated.Lab report chem 200 calorimetry part specific heat capacity lab report name: nadia valencia version: section: 15 revised procedures each trial for the. Skip to document. University; ... Chem 200 lab #3 post lab; Lab …Here you will find the lab report done for Lab Experiment 8 Styrofoam Cup Calorimetry lab report: ch.8 annelise garcia, michael herrera, daniel herrera. Skip to document. University; High School. Books; Discovery. ... Post-lab Questions: It’s a statement that the gram-atomic heat capacity (Specific heat times atomic weight) of an element is a ...

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Experiment 25 Post Lab: Calorimetry. Term. 1 / 5. Part A.1. The 200-mm test tube also contained some water (besides the metal) that was subsequently added to the calorimeter (in Part A.4). Considering a higher specific heat for water, will the temperature change in the calorimeter be higher, lower, or unaffected by this technique error? Explain. Science. Chemistry. Chemistry questions and answers. CHM 2045L- Heat Effects and Calorimetry Post-Lab Sheet: Heat Effects and Calorimetry Name: Show calculations for credit. Be mindful of significant figures. 1. A piece of aluminum with a mass of 32.5 g is heated to 674°C and put into a Syru foam calonnea containing 582 g of water that is ... A calorimeter is a device used to measure the amount of heat involved in a chemical or physical process. For example, when an exothermic reaction occurs in solution in a calorimeter, the heat produced by the reaction is absorbed by the solution, which increases its temperature. When an endothermic reaction occurs, the heat required is absorbed ...Chemistry questions and answers. Lab 6 - Food Calorimetry Lab Post-Laboratory Assignment Class Section: Date: Name: 1. Was your percentage of the cal/g of Frito less than 100% or greater than 100%? 2. Ust some possible reasons for your percentage collected not being 100% 3. If you had held the match under the can while lighting the Frito how ...

Physics questions and answers. Calorimetry: Specific Heat Capacity of a Metal EXPERIMENT E-305 POST-LAB QUESTIONS Show all work on calculations. 1 Enter the data in the spreadsheet file created for this experiment. Print out the graphs For each gaph use ruler to draw in the vertical and horizontal portions of the curves.Question: Data And Report Submission - Constant Pressure Calorimetry (2pts) "Constant Pressure Calorimetry" Yes Are you completing this experiment online? Part A. Heat of Neutralization Table 1. Heat of neutralization data Sample 1 Sample 2 50.2 50.1 [1] Volume of HCl (mL) 25.0 23.8 50.1 50.2 [2] Temperature of HCI (°C) [3] Volume of NaOH (mL ...Study with Quizlet and memorize flashcards containing terms like Beryllium is a rare metal that is gray in color, strong, and lightweight. The following data was obtained from a calorimeter experiment: The specific heat of beryllium is _____ J/g°C 0.124 0.549 1.82 9.61 9520, The lab procedure involves several factors, listed below. Some were variable and some were constant. Label each factor ...Chemistry questions and answers. Calorimetry and Hess's Law Are you completing this experiment online? Yes Heat Capacity of the Calorimeter Table 1: Calorimeter Heat Capacity Measurements Trial 1 Trial 2 Trial 3 Volume of cool water (mL) 50.00 50.00 50.00 Volume of hot water (mL) 50.00 50.00 50.00 Initial temperature of cool water (°C) 22.0 22 ...What's at the top of your holiday gift list? Answer that and post it on Facebook and Amazon will give you $5 off a purchase of $25 or more. This is the largest credit Amazon has ev...Experiment 25 Post Lab: Calorimetry. Term. 1 / 5. Part A.1. The 200-mm test tube also contained some water (besides the metal) that was subsequently added to the calorimeter (in Part A.4). Considering a higher specific heat for water, will the temperature change in the calorimeter be higher, lower, or unaffected by this technique error? Explain.Molar Mass of Citric Acid Using Titration Lab write up; Calorimetry part 1 Lab write up; Analysis of Aluminum-Zinc Alloy; Lab report #9 - professor: Holland Lab TA: Trammel; Chem 200 lab #3 post lab; Lab Report Qualitative Ananlysis; Use of Volumetric Equipment Lab write up; Molar Mass of Citric Acid Using Titration Lab write up; Calorimetry ...Sep 19, 2020 ... Note: Everything can be measured in grams. In the simulation, you can obtain the value of the specific heat capacity of metals and liquids.

This problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Question: Chemistry - Calorimetry and Specific Heat Lab Data & Calculations Trial 1 Room Temp. Water in Calorimeter Trial 2 Cold Water in Calorimeter 1. Mass of metal sample 24.30.

Chemical Engineering questions and answers. Lab Section: Lab Report: Calorimetry and Hess's Law Metal + HCI Reaction Experimental Data Trial 2 16.290g b 30.3879.2909 Assigned Metal: Trial 1 Mass of dry, empty calorimeter Mass of calorimeter plus HCI Mass of HCl used clb-a) 30.38 79 - = 214:0979 Mass of dry, empty beaker d 29: . 1163 Mass of ...May 17, 2011 ... Solutions. Chem Academy · Playlist · 56:24. Go to channel · Energetics 2 | Calorimetry | Enthalpy Change Experiments | A level. The Chemistry ..... 9 Exp. 9: Calorimetry and Hess’ Law . Pre-lab: When 1.104 grams of iron metal are mixed with 26.023 grams of hydrochloric acid in a coffee cup calorimeter, the temperature rises from 25.2 °C to a maximum of 33.5 °C. We are the industry leader in providing support and advice and this comes with every case you send to us. If you have a technical question or need any assistance with Appliance …Chemistry. Chemistry questions and answers. Experiment 3: Thermochemistry Lab Report Part 1: Determination of Heat Capacity of Calorimeter (Calorimeter Constant) Experimental Data Write all units next to the numerical values. Data should be reported to the correct number of significant figures. Table 1 Trial Trial 2 Volume of cold water som 50 ...Nov 8, 2015 ... This is an example of how you calculate the specific heat of a metal from calorimetry data. Note on Significant figures: They were not ...Question: CHM 2045 Heat Efects and Calorimetry Post-Lab Sheet: Heat Effects and Calorimetry Name: Show calculations for credit. Be mindful of significant figures. 1. A piece of aluminum with a mass of 32.5 g is heated to 67.4'C and put into a Styrofoam calorimeter containing 58.2 g of water that is initially at 21.2'C. Assuming no heat is lost ...Despite the dramatic and highly negative decline in economic activity that forced computer traders to hit the stock markets from above on Wednesday, enough portfolio managers faded...Calorimetry is the process of measuring the amount of heat released or absorbed during a. chemical reaction. By knowing the change in heat, it can be determined whethe r a reaction is. exothermic (releases heat) or endothermic (absorbs heat). A …

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Oct 26, 2022 ... Unit 6 (5/3): Calorimetry Lab Practice. Chemistry with Miss Judy•13 views · 2:42 · Go to channel · Gen Chem Sub Plans (5/22). Chemistry with&n...Water has a greater specific heat capacity because the temperature of the water only changed by 5.06 °C, unlike the copper's change of 54.94 °C. The water resisted temperature change more than the copper. 1. Predict: In the Gizmo warm-up, you saw how 200 g of 90 °C copper transfers heat to 200 g of 30.0 °C water. A.Potato chip calorimetry lab answers · Shree ganesh cotton dress material online shopping · Animated promo presenter · Hunting the elements worksheet answer key.. 18.06.2019 — Determine the specific heat capacity of a …The first step in finding answers to different Apex tests in 2016 is to identify online resources that post the tests and answers, which typically include Salesforce.com and Softwa...Question: 1402 Exp 10 Calorimetry Virtual Lab Post-Lab Worksheet (37 pts) Equations from the lab manual: ATTina - Tinitial (2) Cres Cx mass x AT (3) -Gres (4) A immoles of moles of salt (6) AHeutraluation moles of LR specific heat capacity of water: 4.184 1/8°C Part A: Heat of Neutralization HCl + NaOH → NaCl + H20 Sample Dota: M (NaOH): 1 ...CHEM132 GENERAL CHEMISTRY LAB PRACTICE sardonnasiu name: 1221 section: at lab team members: ta: calorimetry: heats of neutralization part heat capacity of the. Skip to document. University; High School. Books; Discovery. ... Experiment 2 post lab; Experiment 3 Post Lab; Indentifying an Unknown Solid by Density; Midterm 1 Study Guide; …Water has a greater specific heat capacity because the temperature of the water only changed by 5.06 °C, unlike the copper's change of 54.94 °C. The water resisted temperature change more than the copper. 1. Predict: In the Gizmo warm-up, you saw how 200 g of 90 °C copper transfers heat to 200 g of 30.0 °C water. A.Chemistry questions and answers; Hess's Law Post Lab Questions (Answer the following questions, making sure to give me a good indication of the question, your answer, AND your rationale). 1. If heat is conserved, why does the calorimeter cool down? 2. If AH were not a state function, would this technique be valid? Explain. 3.The first time a student solved this problem she got an answer of 88 °C. Explain why this is clearly an incorrect answer. Answer a. 81.95 °C. Answer b. This temperature is higher than the starting temperature of the coffee, which is impossible. Click here to see a video of the solutionThis will be done in pairs, using one of your own prototype 2 calorimeter. Place 50 mL 1 M of NaOH into your calorimeter cup and start stirring. Carefully (and wearing safety splash googles, of course), add 50 mL of 1 M acetic acid and close the lid. Record the temperature every 30 sec for 5 minutes.Calorimetry is the science of measuring heat flow. Heat is defined as thermal energy flowing from an object at a higher temperature to one at a lower temperature. For example, if you drop a coin into a cup with hot water, the temperature of the coin will go up until it is at the same temperature as the boiling water. ….

Step 1: Number of calories released: Change in temp. x Grams of water used (10)=# calories released. Step 2: Mass of food burned: Mass of food before- mass of food after=Mass (g) of food burned. Step 3: Divide calories by grams. Step 4: Calories to dietary kilocalories. Divide by 1000. What are Carbohydrates primary purpose?You will use the Calorimetry Lab Gizmo to determine. the specific heat capacities of various substances. 1. On the SIMULATION pane, select Copper. Use the slider to set its Mass to 200 g. Set the. Water mass to 200 g. Check that the Water temp is set to 30.0 °C and the copper’s Temp. is 90 °C. Select the GRAPH tab, and click Play (.Feb 24, 2016 ... 4.03 Calorimeter Lab Answer Key Video. 2.5K ... 3 L1 Specific heat calorimetry lab ... Post Traumatic Growth (5 Secrets Inside the Trial Tappers ...Q10. Calculate the amount of energy produced/per mole of water produced (in kJ/mol). Name Section Experiment 13: Calorimetry and Thermochemistry POST-LABORATORY ASSIGNMENT Express answers with an appropriate number of significant figures and proper units and using scientific notation when necessary appropriate.Post-Polio Health International Including International Ventilator Users Network. 4207 Lindell Blvd, #110 Saint Louis, MO 63108-2930 USA 314-534-0475 314-534-5070 fax. …Question: Calorimetry: Determining the energy in a peanut In this lab, you will use the bomb calorimeter to find the amount of energy stored in a peanut. Using the bomb calorimeter, the system is kept at constant volume. The method measures a temperature change due to the energy released as heat from the combustion of the peanut.Experiment 25 Calorimetry Pre-laboratory Assignment. Course: Gen Chem Lab I (CHEM 005) 153 Documents. University: Howard University. Info. Download.Answer 123 - chem. Introductory University Chemistry I None. POST LAB REPORT EXPERIMENT A experiment calorimetry for the chem 10x …Calorimetry is the process of measuring the amount of heat released or absorbed during a. chemical reaction. By knowing the change in heat, it can be determined whethe r a reaction is. exothermic (releases heat) or endothermic (absorbs heat). A … Calorimetry post lab answers, Chemistry questions and answers; Hess's Law Post Lab Questions (Answer the following questions, making sure to give me a good indication of the question, your answer, AND your rationale). 1. If heat is conserved, why does the calorimeter cool down? 2. If AH were not a state function, would this technique be valid? Explain. 3., 9 Exp. 9: Calorimetry and Hess’ Law Pre-lab: When 1.104 grams of iron metal are mixed with 26.023 grams of hydrochloric acid in a coffee cup calorimeter, the temperature rises from 25.2 °C to a maximum of 33.5 °C. The reaction that occurs is given below. ... Numbered responses to any post lab question. You do not need to re-write the questions., View Lab G.2 chem 101 (1).pdf from CHEM 101 at Jasper Place School. G-11 POSTLAB ASSIGNMENT: EXPERIMENT G - CALORIMETRY Name Lab Period Lab Room TA Show your work - answers without supporting work, You will use the Calorimetry Lab Gizmo to determine the specific heat capacities of various substances. On the SIMULATION pane, select Copper. Use the slider to set its Mass to 200 g. Set the Water mass to 200 g. Check that the Water temp is set to 30 °C and the copper’s Temp is 90 °C. Select the GRAPH tab, and click Play ( ). A., Jan 12, 2021 ... Lab 1 (Hess's law) post-lab tutorial. Roxi ... ALEKS: Solving A Basic Calorimetry Problem ... ALEKS - Using molarity to find solute mass and ..., Calorimetry; Calorimeter constant; Specific heat capacity; Heat of neutralization; Process: Design the calorimetry constant experiment ; Use virtual labs to find specific heat capacity of an unknown metal; Observe the live data steam and use the data to calculate the heat of neutralization; Prior knowledge: 5.2: Specific Heat Capacity, 9 Exp. 9: Calorimetry and Hess’ Law . Pre-lab: When 1.104 grams of iron metal are mixed with 26.023 grams of hydrochloric acid in a coffee cup calorimeter, the temperature rises from 25.2 °C to a maximum of 33.5 °C. , food calories are a way to measure the _______ you get from the _________ you eat. energy; food. true or false. when heat flows into a substance the temperature of a substance will decrease. false. which of the following is a valid unit for specific heat. J/g°C. Study with Quizlet and memorize flashcards containing terms like One food Calorie ..., The first step in finding answers to different Apex tests in 2016 is to identify online resources that post the tests and answers, which typically include Salesforce.com and Softwa..., Poke through a food substance measuring 0.5 grams using the needle with the handle. Turn on fire on the burner. Set the food substance on the needle to fire on the burner. Once the food substance starts to burn, place it under the test tube so the water inside it can absorb heat. Measure the temperature change in the water using the …, 1. When 5.000 grams of ammonia react with an excess of oxygen and CH in a. 4. bomb calorimeter with a total heat capacity of 15.48 kJ/°C, the temperature of the calorimeter and its contents changes from 19.77°C to 33.90°C. Calculate ∆E and ∆H for the following reaction as written: 2 NH. 3 (g), food calories are a way to measure the _______ you get from the _________ you eat. energy; food. true or false. when heat flows into a substance the temperature of a substance will decrease. false. which of the following is a valid unit for specific heat. J/g°C. Study with Quizlet and memorize flashcards containing terms like One food Calorie ..., Experiment 25 – Calorimetry (Enthalpies and Specific Heats) Pre-Lab Hints. Explain how the temperature of the metal and the water bath become equalized, and how that final equalized temperature is measured., It will be determined from your Excel graph. A 25.39 g sample of metal is heated to 98.6°C in a hot water bath until thermal equilibrium is reached. The metal is quickly transferred to 50.0 mL (50.0 g) of water at 22.2°C contained in a calorimeter. The thermal equilibrium temperature of the metal sample plus water mixture is 28.3°C., will use the Calorimetry Lab Gizmo to determine the specific heat capacities. of various substances. On the SIMULATION pane, select Copper. Use the slider to set its Mass to 200 g. Set the Water mass to; 200 g. Check that the Water temp is set to 30 °C and the copper’s Temp is 90 °C. Select the GRAPH. tab, and click Play ( ). A., Feb 29, 2016 ... Hess Law Lab Calculations. 35K views · 8 years ago ... Hess's Law Lab Calculations. Karin Johnson ... 6 Calorimetry Calculations (neutralisation)., Question: EXPERIMENT 7 (CALORIMETRY] DATA SHEET Part A. [Specific Heat of Metal] Unknown No: Zinc metal Mass of Metal (g) Temperature of metal (°C) Mass of calorimeter (8) Mass of calorimeter + Water (8) Mass of water (e) Temperature of water in calorimeter (°C) Ti Maximum temperature of metal and water from graph (°C) TF 11.57 99.4 25.63 125.62 Calculations for, Experiment 6. Calorimetry Purpose. The purpose of this lab is to analyze the change of two common chemical reactions/processes and become more comfortable with calorimetry techniques and processes. Introduction. Calorimetry is the study of the changes in energy of a system by measuring the heat exchanged during a chemical reaction 2., Sep 22, 2021 · heat released by reaction( − qreaction) = heat absorbed by reaction mixture( + qmixture) = (m × c × ΔT)mixture. Here m is the total mass of the reaction mixture (in g), ΔT is the maximum temperature change that occurs during the reaction (in °C), and c is the specific heat capacity of the mixture (in J/g°C). Note that since the ... , Learn about different lab tests and understand common terms to improve your health literacy. Trusted Health Information from the National Institutes of Health October marked Health..., Calorimeters can be used to find a substance’s specific heat capacity. You will use the Calorimetry Lab Gizmo™ to determine the specific heat capacities of various substances. 1. On the SIMULATION pane, select Copper. Use the slider to set its Mass to 200 g. Set the Water mass to 200 g., I've gotten lots of reader questions about Italy's reopening since I was one of the first tourists to visit Italy on a COVID-tested flight last month. Editor’s note: This is a recu..., Chemistry questions and answers. Post lab question reguarding bomb calorimetry: Heat capacity for calorimeter: 10403.64 J/ C Delta H TTCC: -6864.20 kJ/mol Resonance energy benzene: 423.01 kJ/mol ΔE = -7096.54kJ/mol 1. How does the bomb get sealed when it is charged with oxygen gas?, CHEM132 Experiment 10: Calorimetry. purpose. Click the card to flip 👆. 1. understand hess's law and state functions. 2. set up and calibrate a coffee cup calorimeter. 3. determine the calorimetric constants of a coffee cup calorimeter. 4. determine enthalpy of a strong acid with a strong base and compare it to that of a weak acid with a ..., Jan 17, 2016 ... 6 Calorimetry Calculations (neutralisation) ... Acid Base Neutralization Calorimetry Lab ... CHEM113L: Equilibrium Constant Post-lab Analysis., Gmail's Labs section graduates another feature into the mainstream today, pulling offline mail into the general settings pane. It's good news for Google Apps users without much Lab..., Bomb Calorimetry Pre-Lab Assignment Before coming to lab: • Read the lab thoroughly. • Answer the pre-lab questions that appear at the end of this lab exercise. Purpose A bomb calorimeter will be calibrated using a sample of known benzoic acid and then used to determine the calorie content of an unknown corn chip., 17.7: Calorimetry. At one time, calories in foods were measured with a bomb calorimeter. A weighed amount of the food would be placed in the calorimeter and the system was then sealed and filled with oxygen. An electric spark ignited the food-oxygen mixture. The amount of heat released when the food burned gave an idea of the calories present ..., Here’s the best way to solve it. Solution -- In the given question, The data give …. Lab 4: Calorimetry An unknown metal can be identified by its specific heat. In the calorimetry lab, an unknown metal was placed in a test tube surrounded by boiling water at 100.00∘C. Then the metal was transferred to an enclosed styrofoam cup containing ..., View experiment-25-calorimetry-post-lab-answers-quizlet.html from CHEM 100 at Seneca Valley Shs. experiment 25 calorimetry post lab answers quizlet. Acid Neutra experiment 25 calorimetry post lab, Heat is measured in the energy units, Joules (J), calorimetry is the study of heat transferred in a chemical reaction, and a calorimeter is the tool used to measure this heat. It is an insulated apparatus containing a liquid reservoir in …, Chemistry 212 Lab 9 Calorimetry and Hess’s Law 2 A calorimeter is a device that can be used to measure heat flow. The main requirement for a calorimeter is that it be well insulated, so that there is no heat lost to the surroundings during the measurement. If this condition is met, then all the heat produced during a reaction will be retained, %question% Get the answers you need, now! the answers to the Lab: Calorimetry and Specific Heat step3: aluminum- 11.98 copper-12.14 iron- 12.31 - brainly.com See what teachers have to say about Brainly's new learning tools!